|
|
L-phenylalanine <=> Cinnamic_acid + NH3
|
4.3.1.1
aspartate ammonia-lyase
4.3.1.23
tyrosine ammonia-lyase
4.3.1.24
phenylalanine ammonia-lyase
4.3.1.25
phenylalanine/tyrosine ammonia-lyase
4.3.1.31
L-tryptophan ammonia lyase
4.3.1.5
phenylalanine ammonia-lyase
|
–
–
–
–
–
–
|
BMK
|
|
BRENDA:
BR3427;
BS445625
KEGG:
R00697
MetaCyc:
PHENYLALANINE-AMMONIA-LYASE-RXN
SABIO-RK:
1076
|
|
|
|
H+ + Cinnamic_acid + O2 + NADPH <=> H2O + NADP+ + coumaric_acid
|
1.14.13.14
trans-cinnamate 2-monooxygenase
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
–
|
MK
|
|
BRENDA:
BR40436
KEGG:
R02254
MetaCyc:
TRANS-CINNAMATE-2-MONOOXYGENASE-RXN
SABIO-RK:
8733
|
|
|
|
cinnamoyl-CoA + D-phenyllactate <=> Cinnamic_acid + (R)-phenyllactyl-CoA
|
2.8.3.17
3-(aryl)acryloyl-CoA:(R)-3-(aryl)lactate CoA-transferase
|
–
|
BMK
|
|
BRENDA:
BR47452
KEGG:
R07796
MetaCyc:
2.8.3.17-RXN
|
|
|
|
UDP-glucose + Cinnamic_acid <=> UDP + 1-O-cinnamoyl-beta-D-glucose
|
2.4.1.120
sinapate 1-glucosyltransferase
2.4.1.136
gallate 1-beta-glucosyltransferase
2.4.1.177
cinnamate beta-D-glucosyltransferase
|
–
–
–
|
M
|
|
BRENDA:
BR47493;
BS322029
KEGG:
R02256
MetaCyc:
CINNAMATE-GLUCOSYLTRANSFERASE-RXN
|
|
|
|
Cinnamic_acid + H+ <=> Styrene + CO2
|
4.1.1.102
phenacrylate decarboxylase
|
–
|
|
|
BRENDA:
BR51533
KEGG:
R11070
MetaCyc:
RXN-803
|
|
|
|
Cinnamic_acid + CoA + ATP <=> cinnamoyl-CoA + AMP + diphosphate
|
6.2.1
6.2.1.12
4-coumarate---CoA ligase
6.2.1.2
medium-chain acyl-CoA ligase
6.2.1.30
phenylacetate---CoA ligase
|
–
–
–
–
|
MK
|
|
BRENDA:
BS34;
BS400329
KEGG:
R02255
MetaCyc:
RXN-2001
SABIO-RK:
12839;
2225
|
|
|
|
cinnamaldehyde + O2 + H2O <=> H+ + Cinnamic_acid + H2O2
|
1.2.3.1
aldehyde oxidase
1.2.3.9
aryl-aldehyde oxidase
|
–
–
|
|
|
BRENDA:
BS372710
MetaCyc:
RXN-8089
|
|
|
|
S-adenosyl-L-methionine + Cinnamic_acid <=> methyl_cinnamate + S-adenosyl-L-homocysteine
|
2.1.1.274
salicylate 1-O-methyltransferase
|
–
|
M
|
|
BRENDA:
BS424043
MetaCyc:
RXN-6721
|
|
|
|
Cinnamic_acid + NADH + O2 + H+ <=> trans-3-[(5S,6R)-5,6-dihydroxycyclohexa-1,3-dienyl]-acrylic_acid + NAD+
|
1.14.12.19
3-phenylpropanoate dioxygenase
|
–
|
MK
|
|
KEGG:
R06783
MetaCyc:
RXN-12072
|
|
|
|
Cinnamic_acid + NAD+ + H2O <=> benzoate + acetate + NADH + H+
|
not assigned
|
–
|
MK
|
|
KEGG:
R01426
MetaCyc:
RXN-9336
|
|
|
|
cinnamaldehyde + NAD+ + H2O <=> Cinnamic_acid + NADH + H+
|
1.2.1.28
benzaldehyde dehydrogenase (NAD+)
1.2.1.3
aldehyde dehydrogenase (NAD+)
1.2.1.5
aldehyde dehydrogenase [NAD(P)+]
1.2.1.64
4-hydroxybenzaldehyde dehydrogenase (NAD+)
1.2.1.67
vanillin dehydrogenase
|
–
–
–
–
–
|
|
|
BRENDA:
BS231664
SABIO-RK:
6916
|
|
|
|
cinnamaldehyde + H2O + 2,6-dichlorophenolindophenol <=> Cinnamic_acid + reduced_2,6-dichlorophenolindophenol
|
1.2.3.1
aldehyde oxidase
1.2.3.14
abscisic-aldehyde oxidase
1.2.99.7
aldehyde dehydrogenase (FAD-independent)
|
–
–
–
|
|
|
BRENDA:
BS439333
SABIO-RK:
12033
|
|
|
|
UDP-glucose + Cinnamic_acid <=> UDP + cinnamoyl-beta-1-D-glucose
|
2.4.1.121
indole-3-acetate beta-glucosyltransferase
2.4.1.126
hydroxycinnamate 4-beta-glucosyltransferase
|
–
–
|
|
|
BRENDA:
BS452033
SABIO-RK:
13133
|
|
|
|
Cinnamic_acid + H2O <=> 3-hydroxy-3-phenylpropionic_acid
|
not assigned
|
–
|
M
|
|
MetaCyc:
RXN-11269
|
|
|
|
Cinnamic_acid + NH3 <=> (S)-beta-phenylalanine
|
not assigned
|
–
|
|
|
MetaCyc:
RXN-18527
|
|
|
|
3-Phenylpropionic_acid + oxidized_electron_transfer_flavoprotein + H+ <=> Cinnamic_acid + reduced_flavodoxin
|
1.3.8.15
3-(aryl)acrylate reductase
|
–
|
M
|
|
MetaCyc:
RXN-19882
|
|
|
|
Cinnamic_acid + O2 + reduced_[NADPH-hemoprotein_reductase] <=> p-coumaric_acid + H2O + oxidized_[NADPH-hemoprotein_reductase]
|
1.14.14.91
trans-cinnamate 4-monooxygenase
|
–
|
M
|
|
MetaCyc:
TRANS-CINNAMATE-4-MONOOXYGENASE-RXN
|
|
|
|
Cinnamic_acid <=> Cinnamic_acid
|
not assigned
|
–
|
|
|
MetaCyc:
TRANS-RXN0-466
|
|
|
|
cinnamoyl-CoA + H2O <=> Cinnamic_acid + CoA
|
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
|
|
|
BRENDA:
BS411877
|
|
|
|
Cinnamic_acid + reduced_flavodoxin + O2 <=> p-coumaric_acid + flavin + H2O
|
1.14.14.92
benzoate 4-monooxygenase
|
–
|
|
|
BRENDA:
BS289256
|
|
|
|
Cinnamoylcholine + H2O <=> Cinnamic_acid + choline
|
3.1.1.49
sinapine esterase
|
–
|
|
|
BRENDA:
BS64555
|
|
|
|
Cinnamic_acid + NADH <=> 3-Phenylpropionic_acid + NAD+
|
1.3.1.6
fumarate reductase (NADH)
|
–
|
|
|
BRENDA:
BS258623
|
|
|
|
Cinnamic_acid + NADH <=> phenylpropionate + NAD+
|
1.3.1.31
2-enoate reductase
|
–
|
|
|
BRENDA:
BS258441
|
|
|
|
Cinnamic_acid + NAD+ <=> 3-Phenylpropionic_acid + NADH + H+
|
1.3.1.31
2-enoate reductase
|
–
|
|
|
BRENDA:
BS439336
|
|
|
|
Cinnamic_acid + NADH + O2 + H+ <=> cinnamic_acid-2,3-dihydrodiol + NAD+
|
1.14.12.19
3-phenylpropanoate dioxygenase
|
–
|
|
|
BRENDA:
BS376494
|
|
|
|
cinnamaldehyde + H2O + Oxidized_benzyl_viologen <=> Cinnamic_acid + reduced_benzyl_viologen
|
1.2.7.5
aldehyde ferredoxin oxidoreductase
1.2.7.B3
|
–
–
|
|
|
BRENDA:
BS372711
|
|
|
|
Cinnamic_acid + NADPH + ATP <=> cinnamaldehyde + NADP+ + AMP + H2O
|
1.2.1.30
carboxylate reductase (NADP+)
|
–
|
|
|
BRENDA:
BS189193
|
|
|
|
UDP-glucose + Cinnamic_acid <=> UDP + cinnamoyl_3-O-beta-D-glucoside
|
2.4.1.35
phenol beta-glucosyltransferase
|
–
|
|
|
BRENDA:
BS456899
|
|
|
|
Cinnamic_acid_ethylester + H2O <=> Cinnamic_acid + ethanol
|
3.1.1.42
chlorogenate hydrolase
|
–
|
|
|
BRENDA:
BS64478
|
|
|
|
N-cinnamoylglycine + H2O <=> Cinnamic_acid + glycine
|
3.5.1.71
N-feruloylglycine deacylase
|
–
|
|
|
BRENDA:
BS140657
|
|
|
|
5''-O-cinnamoyl-2''-deoxy-5-fluorouridine + H2O <=> Cinnamic_acid + 2''-deoxy-5-fluorouridine
|
3.1.1.1
carboxylesterase
|
–
|
|
|
BRENDA:
BS383964
|
|
|
|
cinnamoyl-L-phenyllactate + H2O <=> Cinnamic_acid + L-Phenyllactate
|
3.4.17.1
carboxypeptidase A
|
–
|
|
|
BRENDA:
BS36705
|
|
|
|
feruloyl_arabinoside + H2O <=> ferulic_acid + coumaric_acid + Cinnamic_acid + arabinose
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS139697
|
|
|
|
trans-cinnamic_acid_ethyl_ester + H2O <=> Cinnamic_acid + ethanol
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS391930
|
|
|
|
cinnamaldehyde + H2O + acceptor <=> Cinnamic_acid + reduced_acceptor
|
1.17.1.4
xanthine dehydrogenase
|
–
|
|
|
BRENDA:
BS439334
|
|
|
|
methyl_cinnamate + H2O <=> Cinnamic_acid + methanol
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS385170
|
|
|
|
cinnamic_acid_methyl_ester + H2O <=> Cinnamic_acid + methanol
|
3.1.1.1
carboxylesterase
3.1.1.73
feruloyl esterase
|
–
–
|
|
|
BRENDA:
BS139694
|
|
|
|
cinnamaldehyde + carbamoyl_methyl_viologen <=> Cinnamic_acid + reduced_carbamoyl_methyl_viologen
|
1.2.99.6
carboxylate reductase
|
–
|
|
|
BRENDA:
BS5752
|
|
|
|
Cinnamonitrile + H2O <=> Cinnamic_acid + NH3
|
3.5.5.1
nitrilase
3.5.5.5
arylacetonitrilase
3.5.5.7
aliphatic nitrilase
|
–
–
–
|
|
|
BRENDA:
BS18171
|
|
|
|
cinnamamide + H2O <=> Cinnamic_acid + NH3
|
3.5.1.4
amidase
|
–
|
|
|
BRENDA:
BS426108
|
|
|
|
triolein + Cinnamic_acid <=> monocinnamoyl_oleoyl_glycerol + dicinnamoyl_oleoyl_glyerol + monocinnamoyl_dioleoyl_glycerol
|
3.1.1.3
triacylglycerol lipase
|
–
|
|
|
BRENDA:
BS402046
|
|
|
|
benzyl_(2E)-3-phenylprop-2-enoate + H2O <=> benzyl_alcohol + Cinnamic_acid
|
3.1.1.73
feruloyl esterase
|
–
|
|
|
BRENDA:
BS429981
|
|